Issue 15, 1971

Mechanism of initiation of cumene autoxidation by palladium(0) complexes

Abstract

Chain initiation in the liquid-phase autoxidation of cumene at 35° catalysed by the palladium(0) complex (Ph3P)4Pd, occurs via hydroperoxide decomposition and not via an “oxygen activation” mechanism.

Article information

Article type
Paper

J. Chem. Soc. D, 1971, 788b-789

Mechanism of initiation of cumene autoxidation by palladium(0) complexes

R. A. Sheldon, J. Chem. Soc. D, 1971, 788b DOI: 10.1039/C2971000788B

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