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The use of α-deuteriated substrates has established that in the lead tetra-acetate oxidation of certain secondary alicyclic and open-chain alcohols, ketone formation proceeds, in part, by 1,4-transfer of hydrogen from the carbinol (α) carbon atom to the δ-carbon atom.
D. Jeremić, S. Milosavljević, V. Andrejević, M. Jakovljević-Marinković, Ž. Čeković and M. Lj. Mihailović, J. Chem. Soc. D, 1971, 1612 DOI: 10.1039/C29710001612
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