Spectroscopic (1H n.m.r. and i.r.), electrical conductivity, and chemical evidence indicates that reactions of π-C5H5Fe(CO)2R, π-C5H5Mo(CO)3R, and Mn(CO)5R (R = alkyl or aryl) with SO2 proceed via the intermediacy of the oxygen-bonded sulphinates, which subsequently rearrange to the thermodynamically stable and isolable sulphur-bonded sulphinates.
S. E. Jacobson, P. Reich-Rohrwig and A. Wojcicki, J. Chem. Soc. D, 1971, 1526 DOI: 10.1039/C29710001526
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