Irradiation of bicyclo[3,2,1]oct-2-en-8-one in hydrocarbon solvents leads to photodecarbonylation as the preferred reaction pathway accompanied to a lesser extent by the previously reported photoisomerization to bicyclo[4,1,1]oct-2-en-8-one.
J. Meinwald and P. J. Vuuren, J. Chem. Soc. D, 1971, 1460 DOI: 10.1039/C29710001460
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