Stable phosphiniminophosphonium salts of the hitherto unknown dimethyltetrafluorophosphate anion, [Me2P(N![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
PR3)2]+[Me2PF4]–, have been prepared in the reaction of dimethyltrifluorophosphorane with several N-trimethylsilylphosphine imines.
W. Stadelmann, O. Stelzer and R. Schmutzler, J. Chem. Soc. D, 1971, 1456 DOI: 10.1039/C29710001456
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