The rotation about the sulphur(IV)–nitrogen bond in SS-dimethyl-N-methylsulphonylsulphilimine (Me2S:N·SO2Me) has been investigated theoretically by the extended Hückel Method; the symmetry properties of the molecule, the anomalies in its n.m.r. spectrum, and the fact that S-symmetrical sulphilimines cannot be resolved into antipodes are explained on the basis of the shape of the total energy curve.
P. Mezey and Á. Kucsman, J. Chem. Soc. D, 1971, 1448 DOI: 10.1039/C29710001448
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