Issue 22, 1971

Carbonyl ylides as possible intermediates in reactions of a mercurial dichlorocarbene precursor with benzaldehyde

Abstract

The intermediacy of a carbonyl ylide is used to explain why treatment of benzaldehyde with phenyl(bromodichloromethyl)mercury produced phenylmercuric bromide, carbon monoxide, benzal halide, and methyl 2,4-diphenyl-3,5-dioxahexanoate as major products.

Article information

Article type
Paper

J. Chem. Soc. D, 1971, 1438-1440

Carbonyl ylides as possible intermediates in reactions of a mercurial dichlorocarbene precursor with benzaldehyde

C. W. Martin, J. A. Landgrebe and E. Rapp, J. Chem. Soc. D, 1971, 1438 DOI: 10.1039/C29710001438

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