Cleavage of the glycosidic linkage occurred during the decomposition, in aqueous medium, of the N-nitroso-derivatives of two 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosides to give 3,4,6-tri-O-acetyl-2,5-anhydro-D-mannose and the aglycone; in non-aqueous medium extensive denitrosation occurred and the aglycone was retained in the products of rearrangement.
J. W. Llewellyn and J. M. Williams, J. Chem. Soc. D, 1971, 1386 DOI: 10.1039/C29710001386
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