The reaction of trisilyl- or trigermyl-arsine with chloro(dimethyl)arsine leads to the formation of pentasilylcyclopenta-arsine, (SiH3As)5, or pentagermylcyclopenta-arsine, (GeH3As)5, respectively; these are the first examples of metalloid-substituted polyarsines.
J. W. Anderson and J. E. Drake, J. Chem. Soc. D, 1971, 1372 DOI: 10.1039/C29710001372
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