Issue 21, 1971

Acid-catalysed rearrangements of 3,5-dimethyl-1-methoxy-tetrafluorobenzobarrelene (5,6,7,8-tetrafluoro-1,4-dihydro-3,10-dimethyl-1-methoxy-1,4-ethenonaphthalene)

Abstract

The title compound undergoes rearrangement in trifluoroacetic acid to afford almost exclusively the benzobarrelenone (2) whereas in concentrated sulphuric acid the lactone (3) is obtained in quantitative yield.

Article information

Article type
Paper

J. Chem. Soc. D, 1971, 1342-1343

Acid-catalysed rearrangements of 3,5-dimethyl-1-methoxy-tetrafluorobenzobarrelene (5,6,7,8-tetrafluoro-1,4-dihydro-3,10-dimethyl-1-methoxy-1,4-ethenonaphthalene)

H. Heaney and S. V. Ley, J. Chem. Soc. D, 1971, 1342 DOI: 10.1039/C29710001342

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