The temperature-dependence of the solution c.d. spectrum of (+)-[Co(tn)3]3+ and the solid-state c.d. of (+)-[Co(tn)3]Br3,H2O indicate a conformational equilibrium in solution between a tris-skew-boat and a trischair form, the latter being the more stable by 0·5 kcal mol–1.
P. G. Beddoe, M. J. Harding, S. F. Mason and B. J. Peart, J. Chem. Soc. D, 1971, 1283 DOI: 10.1039/C29710001283
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