Treatment of the cation [(π-C5H5)2Mo(SMe2)Br]+ with some amines R1R2CHNH2in water gives the amine–hydrides [(π-C5H5)2Mo(NH2CHR1R2)H]+ together with aldehydes or ketones, R1R2CHO,R2= H or alkyl.
F. W. S. Benfield and M. L. H. Green, J. Chem. Soc. D, 1971, 1274 DOI: 10.1039/C29710001274
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