Reductive dehalogenation competes effectively with nucleophilic aromatic substitution in nitro-activated halogeno-compounds when the nucleophile is a bulky amine and the halogen is iodine, but not when it is chlorine or fluorine; a radical mechanism is suggested.
F. Pietra, M. Bartolozzi and F. Del Cima, J. Chem. Soc. D, 1971, 1232 DOI: 10.1039/C29710001232
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