The isonitrile complexes, [M(CNR)4]+, [M(PPh3)2(CNR)2]+, and [M(PPh3)2(CNR)3]+(M = Rh or Ir; R = alkyl or aryl) have been prepared, and undergo oxidative-addition reactions giving [M(CNR)4XY]+[M(PPh3)2(CNR)2XY]+, [M(PPh3)2(CNR)3X]2+, and [M(PPh3)2(CNR)2Y2]+, (X = halogen, methyl, acyl, allyl, HgCl, SnCl3; Y = halogen).
J. W. Dart, M. K. Lloyd, J. A. McCleverty and R. Mason, J. Chem. Soc. D, 1971, 1197 DOI: 10.1039/C29710001197
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