SCHEDULED MAINTENANCE
(±)-[6-3H]-9-Demethylmunduserone (II; R![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
H) is a good precursor for amorphigenin in A. fruticosa and holds a key biosynthetic position; incorporation of (±)-[6-3H]rotenonic acid (III), and [6-3H]mutarotenone into amorphigenin lead to a scheme for the ring-E prenyl elaboration.
L. Crombie, P. M. Dewick and D. A. Whiting, J. Chem. Soc. D, 1971, 1182 DOI: 10.1039/C29710001182
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