The crystal structure of dioxygen–bis(diphenylethylphosphine)chlorocarbonyliridium(I) has been shown to consist of trans-trigonal bipyramidal molecules with an O–O distance of 1·461 (14)Å.
M. S. Weininger, I. F. Taylor and E. L. Amma, J. Chem. Soc. D, 1971, 1172 DOI: 10.1039/C29710001172
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