Hexamethylphosphoric triamide reacts with alkyl iodides to produce a salt of a new type for which the structure (Me2N)3P·O·P(O)(NMe2)2 I– has been established.
C. Anselmi, B. Macchia, F. Macchia and L. Monti, J. Chem. Soc. D, 1971, 1152 DOI: 10.1039/C29710001152
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