Treatment of olefins with SbCl5 in CCl4 gave cis-vic-dichloroalkanes predominantly; e.g. cis- and trans-but-2-enes and cyclohexene gave meso- and (±)-2,3-dichlorobutanes and cis-1,2-dichlorocyclohexane respectively.
S. Uemura, O. Sasaki and M. Okano, J. Chem. Soc. D, 1971, 1064 DOI: 10.1039/C29710001064
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