Acid catalysed conversion of germacrone-type sesquiterpenes into cadinene-type compounds has been carried out by using 80% aq. AcOH or AlCl3 in dry ether, and ε-cadinene has been synthesized from preisocalamendiol in two steps.
M. Iguchi, M. Niwa and S. Yamamura, J. Chem. Soc. D, 1971, 974 DOI: 10.1039/C29710000974
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