In methanol photo-isomerization of biphenyl-2-yl isocyanide (1) requires solvent interaction for the formation of the predominant product phenanthridine (2) but not for the minor product cyclohept[b]indole (3).
J. de Jong and J. H. Boyer, J. Chem. Soc. D, 1971, 961 DOI: 10.1039/C29710000961
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