A novel instance of preferential syn–anti-isomerisation about the substituted carbon atom of an asymmetrically substituted π-allylpalladium chloride dimer is accounted for in terms of an intramolecular, four-co-ordinate σ-allyl transition state.
D. J. S. Guthrie, R. Spratt and S. M. Nelson, J. Chem. Soc. D, 1971, 935 DOI: 10.1039/C29710000935
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