Clear e.s.r. evidence is provided for the formation of NH2 and H2CN radicals during the radiolysis of frozen aqueous solutions of alkali metal azides and cyanides respectively; these unexpected products may be formed by protonation of NH– and HCN–.
I. S. Ginns and M. C. R. Symons, J. Chem. Soc. D, 1971, 893 DOI: 10.1039/C29710000893
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