Issue 15, 1971
From the journal:

Journal of the Chemical Society D: Chemical Communications

Crystal and molecular structure of [Mn(CO)4(C2PPh3)Br]—a co-ordination compound of the unusual carbonyl-ylide product, Ph3P+–C[triple bond, length as m-dash]C:–

Stephen Z. Goldberg,   Eileen N. Duesler  and  Kenneth N. Raymond  

Abstract

The crystal and molecular structure of the reaction product of (Ph3P)2C and Mn(CO)5Br, [Mn(CO)4(C2PPh3)Br], has been determined and the complex found to contain the unusual phosphonium acetylide, Ph3P+–C[triple bond, length as m-dash]C:–.

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Article information

DOI
https://doi.org/10.1039/C29710000826
Article type
Paper

J. Chem. Soc. D, 1971, 826-827

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Crystal and molecular structure of [Mn(CO)4(C2PPh3)Br]—a co-ordination compound of the unusual carbonyl-ylide product, Ph3P+–C[triple bond, length as m-dash]C:–

S. Z. Goldberg, E. N. Duesler and K. N. Raymond, J. Chem. Soc. D, 1971, 826 DOI: 10.1039/C29710000826

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