A new annelation reaction, initiated by the protonated diazomethylcarbonyl function, has been utilized in the incorporation of the bicyclo[3,2,1]octane moiety into a variety of intermediates for the total synthesis of tetracyclic diterpenoids.
D. J. Beames, T. R. Klose and L. N. Mander, J. Chem. Soc. D, 1971, 773 DOI: 10.1039/C29710000773
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