Issue 14, 1971

Evidence for the formation of vibrationally excited triplet 1,3-biradicals in the Hg 3P1 photosensitized decomposition of cis- and trans-3,4-dimethyl-Δ1-pyrazoline

Abstract

Mercury photosensitized decomposition of cis- and trans-3,4-dimethyl-Δ1-pyrazoline vapour yields vibrationally excited triplet biradical intermediates which undergo pressure-dependent isomerizations to form olefins or cyclization to dimethylcyclopropanes.

Article information

Article type
Paper

J. Chem. Soc. D, 1971, 742-743

Evidence for the formation of vibrationally excited triplet 1,3-biradicals in the Hg 3P1 photosensitized decomposition of cis- and trans-3,4-dimethyl-Δ1-pyrazoline

E. B. Klunder and R. W. Carr, J. Chem. Soc. D, 1971, 742 DOI: 10.1039/C29710000742

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