Labelling studies with Penicillium herquei have shown that atrovenetin is incorporated into herqueinone via deoxyherqueinone, requiring sequential methylation and oxidation: norherqueinone is derived oxidatively from atrovenetin, but is not methylated to form herqueinone.
A. B. Kriegler and R. Thomas, J. Chem. Soc. D, 1971, 738 DOI: 10.1039/C29710000738
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