Since NdSO4+ formation was slowed by a factor of 2·3 in D2O as compared with H2O while the dissociation was accelerated, the Eigen complexation mechanism predicting cation–solvent exchange as the slow step, cannot be the controlling mechanism in lanthanoid complexation reactions.
H. B. Silber, J. Chem. Soc. D, 1971, 731 DOI: 10.1039/C29710000731
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