Enthalpy and entropy changes in the formation of chelated complexes in aqueous solution between Ag+ and some thio- and seleno-alkenes demonstrate the thermodynamic origin of the symbiotic effect and the importance of using the lowest possible temperatures for reactions involving the co-ordination of olefins.
D. S. Barnes, G. J. Ford, L. D. Pettit and C. Sherrington, J. Chem. Soc. D, 1971, 690 DOI: 10.1039/C29710000690
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