SCHEDULED MAINTENANCE
The crystal structure of tetrabenzylzirconium (at –40 °C) shows the molecule to have approximate ![[4 with combining macron]](https://www.rsc.org/images/entities/char_0034_0304.gif)
symmetry with distorted tetrahedral co-ordination (average Zr–C 2·27 Å); the benzyl groups are σ-bonded to the metal atom but the angles at the methylene carbon atoms are unexpectedly small, ranging from 85° to 101°.
G. R. Davies, J. A. J. Jarvis, B. T. Kilbourn and A. J. P. Pioli, J. Chem. Soc. D, 1971, 677 DOI: 10.1039/C29710000677
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