Issue 11, 1971

β-Secondary deuterium isotope effects as a measure of charge localization in carbonium ion reactions: the existence of a major inconsistency in interpretation

Abstract

In contrast to published interpretations, the solvolytic β-deuterium isotope effects for secondary and tertiary norborn-2-yl-derivatives are qualitatively inconsistent with anchimerically assisted solvolysis for exo-secondary substrates.

Article information

Article type
Paper

J. Chem. Soc. D, 1971, 592-593

β-Secondary deuterium isotope effects as a measure of charge localization in carbonium ion reactions: the existence of a major inconsistency in interpretation

S. E. Scheppele, J. Chem. Soc. D, 1971, 592 DOI: 10.1039/C29710000592

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements