The different bonding modes exhibited by the co-ordinated thiocyanate ion when the complex trans-Co-(dmg)2(Py)(SCN) is dissolved in high or low dielectric constant solvents have been shown to be kinetically controlled, rather than thermodynamically controlled, as was previously proposed by other workers.
R. L. Hassel and J. L. Burmeister, J. Chem. Soc. D, 1971, 568 DOI: 10.1039/C29710000568
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