The rate of olefin isomerization catalysed by RuCl2(Ph3P)3 is greatly accelerated in the presence of small amount of hydroperoxides which convert the ruthenium complex into a catalytically active compound having a CO ligand.
J. E. Lyons, J. Chem. Soc. D, 1971, 562 DOI: 10.1039/C29710000562
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