Detailed analysis of a number of exocyclic olefins has shown that the sign of π→π* absorption can be related to absolute configuration by use of the Octant rule.
M. Fetizon, I. Hanna, A. I. Scott, A. D. Wrixon and T. K. Devon, J. Chem. Soc. D, 1971, 545 DOI: 10.1039/C29710000545
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