Issue 10, 1971
From the journal:

Journal of the Chemical Society D: Chemical Communications

Rates of chelate ring closure and opening at a chromium(III)–thiol bond

Robert H. Lane  and  Larry E. Bennett  

Abstract

The rates of chelate ring opening, (70[H+]+0·6)× 10–6[Cr(H2O)4(SCH2CO2)+], and closure, (70 + 0·8[H+]–1)× 10–7[Cr(H2O)5(O2CCH2SH)2+], at the Cr–S bond appear to parallel other substitutions at CrIII with no apparent abnormalities associated with the mercaptan function and a 100-fold rate advantage for chelate closure by both paths.

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Article information

DOI
https://doi.org/10.1039/C29710000491
Article type
Paper

J. Chem. Soc. D, 1971, 491-492

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Rates of chelate ring closure and opening at a chromium(III)–thiol bond

R. H. Lane and L. E. Bennett, J. Chem. Soc. D, 1971, 491 DOI: 10.1039/C29710000491

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