Spectroscopic evidence indicates that aliphatic dinitriles σ-bond in M(CO)3(dinitrile)X complexes (M = Mn and Re; X = Cl, Br, and I) using one donor nitrogen atom only, and do not act as π-bonding chelates as previously suggested.
J. G. Dunn and D. A. Edwards, J. Chem. Soc. D, 1971, 482 DOI: 10.1039/C29710000482
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