Chiral phosphonates reacted with P4S10 to give their thionoanalogues with predominant (if not complete) retention of configuration; basic hydrolysis of the phosphonothionates gave completely recemic products.
L. P. Reiff, L. J. Szafraniec and H. S. Aaron, J. Chem. Soc. D, 1971, 366 DOI: 10.1039/C29710000366
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