Issue 7, 1971
From the journal:

Journal of the Chemical Society D: Chemical Communications

Mono-olefin chelate complexes of iron(0) and ruthenium(0) with an olefinic tertiary phosphine

M. A. Bennett,   G. B. Robertson,   I. B. Tomkins  and  P. O. Whimp  

Abstract

Reaction of 2-vinylphenyl(diphenyl)phosphine, o-CH2: CH·C6H4·PPh2(sp), with M3(CO)12(M = Fe or Ru) gives monomeric complexes M(CO)3(sp) and M(CO)2(sp)2; the former are chelate mono-olefin complexes containing bidentate (sp), while Fe(CO)2(sp)2 is shown by our X-ray structural analysis to contain a bidentate (sp) ligand, and a monodentate P-bonded (sp) moiety, in a configuration approximating to a trigonal bipyramid.

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Article information

DOI
https://doi.org/10.1039/C29710000341
Article type
Paper

J. Chem. Soc. D, 1971, 341-342

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Mono-olefin chelate complexes of iron(0) and ruthenium(0) with an olefinic tertiary phosphine

M. A. Bennett, G. B. Robertson, I. B. Tomkins and P. O. Whimp, J. Chem. Soc. D, 1971, 341 DOI: 10.1039/C29710000341

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