In the molecular structures of the bis-(5,5-diethylbarbiturato)-bisimidazole complexes of cobalt(II) and zinc(II) there is tetrahedral co-ordination of the metal atom by nitrogen atoms, and a conformation stabilized by C–H ⋯ O intramolecular interactions between almost coplanar pairs of imidazole and barbiturate rings.
B. C. Wang and B. M. Craven, J. Chem. Soc. D, 1971, 290 DOI: 10.1039/C29710000290
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