The crystal structure of cis-4,6-dimethyl-2-oxo-2-triphenylmethyl-1,3,2-dioxaphosphorinan shows the 1,3,2-dioxaphosphorinan ring to be much more distorted than in related structures, and to have the ‘half-chair’ conformation.
M. G. B. Drew, J. Rodgers, D. W. White and J. G. Verkade, J. Chem. Soc. D, 1971, 227 DOI: 10.1039/C29710000227
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