The anti-1,6 : 8,13-bismethano[14]annulene ligand is non-planar and contains a mainly localised double-bond system: the chromium atom makes short contacts with only five carbon atoms of the ligand and these are in the end ring which contains only two double bonds.
M. J. Barrow and O. S. Mills, J. Chem. Soc. D, 1971, 220 DOI: 10.1039/C29710000220
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