Rhodium complexes in which two azoarene groups act as chelating ligands have been obtained both from rhodium trichloride and from rhodium carbonyl chloride and shown to yield bis(arylazo)biphenyls on carbonylation; the structure of the mononuclear bis(azoarene)rhodium acetate has been established by X-ray crystallography.
A. R. M. Craik, G. R. Knox, P. L. Pauson, R. J. Hoare and O. S. Mills, J. Chem. Soc. D, 1971, 168 DOI: 10.1039/C29710000168
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