In the homogeneous hydrogenation of eight membered cyclo-olefins, o- and p-dihydroxybenzene were superior to alcohols as hydrogen donors, and FeCl2(PPh3)2 and FeBr2(PPh3)2 were the most active catalysts of the complexes MX2(PPh3)2, where M is FeII, CoII, and NiII, and X is Cl–, Br–, and I–.
T. Nishiguchi and K. Fukuzumi, J. Chem. Soc. D, 1971, 139 DOI: 10.1039/C29710000139
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