Reaction of the protonic acids, HCo(PF3)4 and HCo(CO)4, with NN-dimethyl(trimethylsilyl)amine to form silylammonium compounds
Abstract
HCo(PF3)4 and HCo(CO)4 react with Me2NSiMe3 to form [Me2N(H)SiMe3]+[Co(PF3)4]– and [Me2N(H)SiMe3]+[Co(CO)4]–, respectively; the last compound is also formed from the reaction of Me2NH with Me3SiCo(CO)4.