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Volume 66, 1970
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Solvent effects on the activation volume of a Diels-Alder reaction

Abstract

The kinetics of the isoprene+maleic anhydride reaction have been studied in various solvents at pressures up to 1400 atm. The solvent effect on the activation volumes and energies at 35°C are reported. It is shown how the solvent effect on activation volumes is useful both for mechanistic interpretation as well as for determination of the dipole moment of the transition state.

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Article type: Paper
DOI: 10.1039/TF9706602579
Citation: Trans. Faraday Soc., 1970,66, 2579-2584
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    Solvent effects on the activation volume of a Diels-Alder reaction

    R. A. Grieger and C. A. Eckert, Trans. Faraday Soc., 1970, 66, 2579
    DOI: 10.1039/TF9706602579

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