The configurational properties of the peptide group (—C′O—NH—) in a number of secondary amides of the type R·C′ONH·R′ depend on the steric and polar properties of R and R′. In view of this dependence, a torsional oscillator model for the trans peptide group is proposed.
R. L. Jones, Trans. Faraday Soc., 1970, 66, 2491 DOI: 10.1039/TF9706602491
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