The real standard entropy of ions in water is calculated from the temperature coefficient of the outer potential difference between a solution and the metal phase of an electrode reversible to one of the ions in the solution. Sone related real single-ion thermodynamic properties are derived; the value of the temperatures coefficient of the surface potential of water has been evaluated to within ±40 µV K–1.
D. J. Schiffrin, Trans. Faraday Soc., 1970, 66, 2464 DOI: 10.1039/TF9706602464
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