SCHEDULED MAINTENANCE
Studies have been made at 500°C of the second limit, and of the induction period and maximum rate of the slow reaction, of D2+ O2+ N2 mixtures in aged boric-acid-coated vessels. The results enable the velocity constant ratios k11D/k½10D, k8D/k2Dk½10D, k14D/k2D and k15D/k1D, to be evaluated. From a comparison of the rates and peroxide concentrations in the hydrogen and deuterium systems, a value of k7D can be obtained.
R. R. Baldwin, B. N. Rossiter and R. W. Walker, Trans. Faraday Soc., 1970, 66, 2004 DOI: 10.1039/TF9706602004
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