The microwave spectra of five isotopic species of cyclopentadienyl nickel nitrosyl, C5H5NiNO, have been measured, from which the C5ν symmetry of the molecule is confirmed and the structural parameters found to be N—O = 1.165 ± 0.005 Å, Ni—N = 1.626 ± 0.005 Å, Ni—C = 2.11 ± 0.01 Å, C—C = 1.43 ± 0.01 Å and C—H = 1.09 Å(assumed).
A. P. Cox and A. H. Brittain, Trans. Faraday Soc., 1970, 66, 557 DOI: 10.1039/TF9706600557
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