Issue 19, 1970

Optical rotatory dispersion and circular dichroism. Part LXIX. Camphor derivatives; ‘anti-Octant’ behaviour of hydroxy- and acetoxysubstituents

Abstract

C.d. and o.r.d. data are reported for the epimeric 3-hydroxy- and 3-acetoxy-derivatives of (+)-bornan-2-one [(+)-camphor], and the 2-hydroxy- and 2-acetoxy-derivatives of (–)-bornan-3-one [(–)-epi-camphor]. The observed contributions of hydroxy- or acetoxy-groups to amplitudes or Δε values are in the opposite sense to that predicted for alkyl groups by the Octant Rule.

Article information

Article type
Paper

J. Chem. Soc. C, 1970, 2678-2682

Optical rotatory dispersion and circular dichroism. Part LXIX. Camphor derivatives; ‘anti-Octant’ behaviour of hydroxy- and acetoxysubstituents

L. Bartlett, D. N. Kirk, W. Klyne, S. R. Wallis, H. Erdtman and S. Thorén, J. Chem. Soc. C, 1970, 2678 DOI: 10.1039/J39700002678

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