Microbial hydroxylation of liguloxide with Mucor parasiticus gave 7α-hydroxy-, 8α-hydroxy-, 3α-hydroxy-, 8β-hydroxy-, 9α-hydroxy-, and 2β,7α-dihydroxy-liguloxide. The results were compared with respect to steric considerations with the results previously obtained on hydroxylation of guaioxide, the C-4 epimer of liguloxide, with the same fungus.
E. Funke, T. Tozyo, H. Ishii and K. Takeda, J. Chem. Soc. C, 1970, 2548 DOI: 10.1039/J39700002548
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